ΔH Solution Equation:
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The ΔH (enthalpy change) solution equation calculates the heat absorbed or released during a process at constant pressure. The integral form accounts for temperature-dependent heat capacity.
The calculator uses the simplified equation:
Where:
Explanation: This assumes constant Cp over the temperature range. For more precise calculations, integration of Cp(T) would be needed.
Details: Enthalpy change is fundamental in thermodynamics for understanding heat flow in chemical reactions, phase changes, and solution processes.
Tips: Enter heat capacity in J/mol·K and temperature change in Kelvin. The calculator assumes constant Cp over the temperature range.
Q1: What if Cp varies with temperature?
A: For precise calculations, you would need to integrate Cp(T) over the temperature range using temperature-dependent Cp equations.
Q2: What are typical Cp values?
A: For water: ~75 J/mol·K, many organic liquids: 100-200 J/mol·K, metals: ~25 J/mol·K.
Q3: When is this approximation valid?
A: When Cp doesn't change significantly over the temperature range of interest (typically small ΔT).
Q4: How does this relate to chemical reactions?
A: ΔH of reaction can be calculated from product and reactant enthalpies using Hess's Law.
Q5: What about phase changes?
A: Phase changes require additional terms for latent heat (ΔH_fusion or ΔH_vaporization).