Delta H Solution Equation:
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The ΔH_solution equation calculates the enthalpy change when a solute dissolves in a solvent. It's the sum of the lattice energy (ΔH_lattice) and the hydration energy (ΔH_hydration).
The calculator uses the Delta H solution equation:
Where:
Explanation: The equation shows that the enthalpy of solution depends on the balance between the energy needed to break the crystal lattice and the energy released when water molecules surround the ions.
Details: The enthalpy of solution helps predict whether a substance will dissolve spontaneously and whether the process will be exothermic or endothermic.
Tips: Enter both ΔH_lattice and ΔH_hydration values in kJ/mol. ΔH_lattice is typically positive (endothermic) while ΔH_hydration is typically negative (exothermic).
Q1: What does a negative ΔH_sol value mean?
A: A negative ΔH_sol indicates the dissolution process is exothermic (releases heat).
Q2: What does a positive ΔH_sol value mean?
A: A positive ΔH_sol indicates the dissolution process is endothermic (absorbs heat).
Q3: How are ΔH_lattice and ΔH_hydration determined experimentally?
A: ΔH_lattice is calculated from Born-Haber cycles, while ΔH_hydration is measured using calorimetry.
Q4: Why do some endothermic processes still occur spontaneously?
A: Dissolution is driven by both enthalpy (ΔH) and entropy (ΔS) changes, as described by ΔG = ΔH - TΔS.
Q5: How does temperature affect ΔH_sol?
A: While ΔH_sol has some temperature dependence, it's often treated as constant over moderate temperature ranges.